The infrared dielectric function of solid para-hydrogen
نویسندگان
چکیده
منابع مشابه
Infrared spectrum of the 2-chloroethyl radical in solid para-hydrogen.
The addition reaction of chlorine with ethylene (C(2)H(4)) is expected to proceed via a free radical intermediate, the 2-chloroethyl radical, however, this intermediate has not been previously observed spectroscopically. Irradiation at 365 nm of a co-deposited mixture of Cl(2), C(2)H(4), and p-H(2) at 3.2 K produces a series of new lines in the infrared spectrum. A strong line at 664.0 cm(-1) a...
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Protonated polycyclic aromatic hydrocarbons (HPAHs) have been reported to have infrared (IR) bands at wavenumbers near those of unidentified infrared (UIR) emission bands from interstellar objects. We produced 1-C16H11 + and 1-C16H11 upon electron bombardment during matrix deposition of p-H2 containing pyrene (C16H10) in a small proportion. Intensities of absorption features of 1-C16H11 + decre...
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The complex dielectric response function of zincblende ZnS is determined a t 300 K by dispersive Fourier transform spectroscopy. The frequency range studied, 150 to 450 cm-l, spans the frequency of the q = 0 transverse optic (TO) phonon mode. The frequency dependence of the anharmonic self-energy function T(Y) of the q = 0 TO phonon is calculated from these data. The features observed in the sp...
متن کاملReactions between chlorine atom and acetylene in solid para-hydrogen: infrared spectrum of the 1-chloroethyl radical.
We applied infrared matrix isolation spectroscopy to investigate the reactions between Cl atom and acetylene (C₂H₂) in a para-hydrogen (p-H₂) matrix at 3.2 K; Cl was produced via photodissociation at 365 nm of matrix-isolated Cl₂ in situ. The 1-chloroethyl radical (·CHClCH₃) and chloroethene (C₂H₃Cl) are identified as the main products of the reaction Cl + C₂H₂ in solid p-H₂. IR absorption line...
متن کاملInfrared spectra of the 1-pyridinium (C5H5NH+) cation and pyridinyl (C5H5NH and 4-C5H6N) radicals isolated in solid para-hydrogen.
Protonated pyridine and its neutral counterparts (C5H6N) are important intermediates in organic and biological reactions and in the atmosphere. We have recorded the IR absorption spectra of the 1-pyridinium (C5H5NH(+)) cation, 1-pyridinyl (C5H5NH), and 4-pyridinyl (4-C5H6N) produced on electron bombardment during matrix deposition of a mixture of pyridine (C5H5N) and p-H2 at 3.2 K; all spectra ...
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ژورنال
عنوان ژورنال: Monthly Notices of the Royal Astronomical Society
سال: 2015
ISSN: 0035-8711,1365-2966
DOI: 10.1093/mnras/stv691